On the construction of 2-substituted 1,4-diacetoxybutadiene moiety: application to the synthesis of (±)-caulerpenyne
作者: Laurent CommeirasMaurice SantelliJean-Luc Parrain
作者单位: 1Laboratoire de Synthèse Organique associé au CNRS (UMR 6009), Faculté des Sciences de Saint Jérôme, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France
刊名: Tetrahedron Letters, 2003, Vol.44 (11), pp.2311-2314
来源数据库: Elsevier Journal
DOI: 10.1016/S0040-4039(03)00235-1
原始语种摘要: Abstract(#br)The synthesis of 2-substituted 1,4-diacetoxybutadiene derivatives with a partial control of stereochemistry is described from two potentially precursor enals by a judicious choice of experimental conditions (Ac 2 O/DMAP in Et 3 N). These conditions have been successfully applied in the first total synthesis of caulerpenyne.
全文获取路径: Elsevier  (合作)
影响因子:2.397 (2012)