Synthesis of [ 3 H 2 ]-(11 S ,17 R )-11,17-Dimethylhentriacontane: a Useful Tool for the Study of the Internalisation of Communication Pheromones of Ant Camponotus vagus
作者: Delphine PempoJean-Christophe CintratJean-Luc ParrainMaurice Santelli
作者单位: 1Laboratoire de Synthèse Organique, esa CNRS 6009, Faculté des Sciences de Saint-Jérôme, F-13397 Marseille Cedex 20, France
2Service des Molécules Marquées, Bat 547, CEN saclay, F-91191 Gif/Yvette, France
刊名: Tetrahedron, 2000, Vol.56 (30), pp.5493-5497
来源数据库: Elsevier Journal
DOI: 10.1016/S0040-4020(00)00447-6
关键词: pheromonetotal synthesisdimethylhentriacontanecitronellolcitronellaltritium
原始语种摘要: Abstract(#br)The convergent synthesis in high enantiomeric and diastereoisomeric purity of [ 3 H 2 ]-(11 S ,17 R )-11,17-dimethylhentriacontane, a communication pheromone of ant Camponotus vagus is described. The stereogenic centres were introduced from commercially available ( S )-citronellol and ( R )-citronellal and the tritiation step was conducted in the last step of the synthesis with tritium gas over the Wilkinson catalyst.
全文获取路径: Elsevier  (合作)
影响因子:2.803 (2012)