Acid-catalyzed regioselective sulfamination of γ-amino–alkenes and stereoselective rearrangement of pyrrolidines to piperidines
作者: Lijun LiHaining WangDeshun HuangYian Shi
作者单位: 1Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
2Department of Chemistry, Colorado State University, Fort Collins, CO 80523, United States
刊名: Tetrahedron, 2012, Vol.68 (47), pp.9853-9859
来源数据库: Elsevier Journal
DOI: 10.1016/j.tet.2012.08.043
关键词: SulfaminationThiiranium ionsRearrangementAcid-catalyzedRegioselectiveStereoselective
英文摘要: Abstract(#br)This paper describes efficient acid-catalyzed regioselective sulfamination of γ-amino–alkenes to form pyrrolidines and stereoselective rearrangement of pyrrolidines to piperidines. A possible reaction mechanism has been proposed.
全文获取路径: Elsevier  (合作)
影响因子:2.803 (2012)