Quantitative in situ microanalysis of minor and trace elements in biogenic calcite using infrared laser ablation – inductively coupled plasma mass spectrometry: a critical evaluation
作者: Erika Vander PuttenFrank DehairsLuc AndréWilly Baeyens
作者单位: 1Laboratorium voor Analytische Chemie, Faculteit Wetenschappen, Vrije Universiteit Brussel, Pleinlaan 21050 BrusselBelgium
2Departement Geologie, Laboratorium voor Petrografie en Mineralogie, Koninklijk Museum voor Midden-Afrika, Leuvensesteenweg 133080 TervurenBelgium
刊名: Analytica Chimica Acta, 1999, Vol.378 (1), pp.261-272
来源数据库: Elsevier Journal
DOI: 10.1016/S0003-2670(98)00613-8
关键词: Infrared laser ablation–inductively coupled plasma mass spectrometryIn situ microanalysisBiogenic calciteInternal standardCalibration standard
原始语种摘要: Abstract(#br)This study evaluates the possibilities and limitations of infrared laser ablation – inductively coupled plasma mass spectrometry, using 43 Ca as internal standard and the silicate glass reference materials NIST 610/612 as calibration standards, for quantifying the spatiotemporal variations of Mg, Mn, Sr, Ba and Pb in the calcite layer of Mytilus edulis shells. It demonstrates that the ablation behaviour of Ca relative to those of the analytes is dependent on the ablation time and substrate matrix (inorganic and biogenic calcite versus NIST 610/612); however, for ablation times ≤80s, internal standardization with Ca improves precision to <10% relative standard deviation (RSD) for all tested substrates. Variations in the Ca distribution in the studied shells...
全文获取路径: Elsevier  (合作)
影响因子:4.387 (2012)