Synthesis, characterization, thermal and computational studies of novel tetra–azido compounds as energetic plasticizers
作者: Mohammad Hadi BaghersadAzizollah HabibiAkbar Heydari
作者单位: 1Faculty of Chemistry, Kharazmi University, No. 43, P. Code 15719-14911, Mofatteh Street, Enghelab Ave., Tehran, Iran
2Chemistry Department, Tarbiat Modarres University, P O Box 14115-175, Tehran, Iran
刊名: Journal of Molecular Structure, 2017, Vol.1130 , pp.447-454
来源数据库: Elsevier Journal
DOI: 10.1016/j.molstruc.2016.09.028
关键词: Azido compoundsEnergetic plasticizersThermal analysisComputational study
英文摘要: Abstract(#br)In this paper, four azido compounds have been synthesized and characterized as new energetic plasticizers. Nuclear magnetic resonance (NMR) and infrared (IR) spectroscopy, elemental analysis, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and differential thermal analysis (DTA) have been used to identify and determine the properties of the synthesized plasticizers. The plasticization effect of plasticizers on glycidyl azide polymer (GAP) has been investigated by viscosity measurements and thermal analysis of the prepolymer–plasticizer mixtures and plasticized binders. The plasticized mixtures were cured by a diisocyanate curing agent and the glass transition temperature and decomposition temperature of the cured polyurethane binders were measured....
全文获取路径: Elsevier  (合作)
影响因子:1.404 (2012)

  • thermal 热的
  • computational 计算的
  • energetic 能量的
  • tetra 表示四
  • compounds 化合物
  • novel 长篇小说