Copper-catalyzed selective ortho -arylations of 2-naphthol and phenol derivatives with diaryliodonium salts
作者: Xiaofei QianJianwei HanLimin Wang
作者单位: 1Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, PR China
2Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, The Chinese Academy of Sciences, 345 Ling Ling Road, Shanghai 200237, PR China
刊名: Tetrahedron Letters, 2016, Vol.57 (5), pp.607-610
来源数据库: Elsevier Journal
DOI: 10.1016/j.tetlet.2015.12.100
关键词: ArylationCoupling reactionDiaryliodonium salt2-NaphtholBiaryls
英文摘要: Abstract(#br)The selective arylations of 2-naphthol and phenol derivatives catalyzed by Cu(OTf) 2 with using diaryliodonium(III) salts have been developed. With this method, biaryls bearing hydroxyl groups can be easily accessed in moderate to good yields. Additionally, this protocol provided an alternative for the preparation of 3-arylated binaphthalene derivatives.
全文获取路径: Elsevier  (合作)
影响因子:2.397 (2012)

  • catalyzed 催化的
  • derivatives 派生物
  • selective 选择性的
  • naphthol 萘酚
  • salts 盐类
  • reaction 反酌
  • phenol 
  • ortho 垂直