Synthesis of 2,3- O -benzyl-ribose and xylose and their equilibration
作者: Reignier JeffreyGurdial SinghPatrice G.J. Plaza-AlexanderNadia SinghJonathan M. GoodmanAlessia BacchiFrancesco Punzo
作者单位: 1Department of Chemistry, University of the West Indies, St. Augustine, Trinidad and Tobago
2Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK
3Dipartimento di Chimica, Università degli Studi di Parma, Parco Area delle Scienze 17/A, Parma 43124, Italy
4Dipartimento di Scienze del Farmaco, Sezione Chimica, Università di Catania, Viale Andrea Doria, 6, 95125 Catania, Italy
刊名: Tetrahedron: Asymmetry, 2014, Vol.25 (20-21), pp.1424-1429
来源数据库: Elsevier Journal
DOI: 10.1016/j.tetasy.2014.09.004
原始语种摘要: Abstract(#br)The preparation and NMR analysis of 2,3-di- O -benzyl d -ribose and 2,3-di- O - d -xylose are described. In DMSO- d 6 the sugars adopt a conformation in which the hydroxyl groups are in an equatorial position. In CDCl 3 and CD 2 Cl 2 the sugars adopts a conformation in which intramolecular hydrogen bonding plays an important role in determining the equilibrium composition. These findings were also confirmed by DFT studies and, in the solid phase, by X-ray single crystal diffraction.
全文获取路径: Elsevier  (合作)
影响因子:2.115 (2012)

  • equilibration 平衡化
  • benzyl 苄基
  • ribose 核糖
  • their 他们的
  • xylose 木糖