Improving methods of CaO transesterification activity
作者: A. EsipovichS. DanovA. BelousovA. Rogozhin
作者单位: 1Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 49, str. Gaidar, Nizhny Novgorod region, Dzerzhinsk 606026, Russia
2Lobachevsky State University of Nizhni Novgorod, National Research University, 23, Gagarin Avenue, Nizhny Novgorod, 603950, Russia
刊名: Journal of Molecular Catalysis. A, Chemical, 2014, Vol.395 , pp.225-233
来源数据库: Elsevier Journal
DOI: 10.1016/j.molcata.2014.08.011
关键词: TransesterificationBiodieselCalcium oxideCalcium glyceroxide
原始语种摘要: Abstract(#br)The activation methods to improve the activity, basicity and stability of CaO as the catalyst for the transesterification of soybean oil have been investigated.(#br)It was determined that calcium glyceroxide complex is formed during the transesterification and acts as the most active phase. Moreover, it was observed that the catalytic activity of spent calcium oxide after transesterification was significantly increased comparing to the fresh catalyst. Thus, activation with glycerol is more efficient technique for the increasing of the CaO transesterification activity compare to the traditional techniques such as thermal treatment and activation with methanol. The synthesized calcium glyceroxide catalyst showed the highest catalytic activity. Under the study conditions, with a...
全文获取路径: Elsevier  (合作)
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影响因子:3.187 (2012)

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