Coordination complexes of Mn(II), Co(II), Ni(II), Zn(II) and Cd(II) with histaminol – Crystal structures and formation constants in aqueous solution
水溶液中Mn(II)、Co(II)、Ni(II)、Zn(II)和Cd(II)与组胺基晶体结构和形成常数的配合物
作者: Piotr MaślewskiDariusz WyrzykowskiWeronika KentnerAnna CiborskaAnna Dołęga
作者单位: 1Department of Inorganic Chemistry, Faculty of Chemistry, Gdansk University of Technology, 11/12 Gabriela Narutowicza Str., 80-233 Gdansk, Poland
2Department of General and Inorganic Chemistry, Faculty of Chemistry, University of Gdańsk, 63 Wita Stwosza Str., 80-308 Gdańsk, Poland
刊名: Polyhedron, 2020, Vol.178
来源数据库: Elsevier Journal
DOI: 10.1016/j.poly.2019.114328
关键词: HistaminolD-block metal cationsCoordination complexesStability constantsX-ray molecular structures
英文摘要: Abstract(#br)Metal binding properties of histaminol (4(5)-(2-hydroxyethyl)imidazole)-natural imidazole derivative – towards several metal ions were investigated in aqueous solution and solid state. Potentiometric titrations returned stability constants for the title histaminol complexes. The stability of the investigated complexes was compared to analogous complexes with 1 H -imidazole and histamine ligands. The ability of histaminol to form chelate complexes and a high tendency to occur in this role in complex compounds has been confirmed by the isolation of some of the complex species in the monocrystalline form and X-ray diffraction measurements. Solid state studies allowed further identification of the important complex species and the comparison of geometrical parameters of...
全文获取路径: Elsevier  (合作)
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影响因子:1.813 (2012)

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关键词翻译
关键词翻译
  • Interactive Interface 公司
  •  公司
  • 元素锌的符号 公司
  • constants 恒有种
  • Co 公司
  • II 公司
  • Ni 公司
  • Zn 公司
  • block 滑车
  • aqueous 水的
  • formation 建造
  • complexes 联合企业
  • molecular 分子的