Polyacrylic acid as mesoscale template for synthesis of MFI zeolite with plentiful intracrystalline mesopores
作者: Dongxue GuoChengxiang ShiHui ZhaoRui ChenShaohua ChenPingchuan SunTiehong Chen
作者单位: 1Institute of New Catalytic Materials Science, School of Materials Science and Engineering, Key Laboratory of Advanced Energy Materials Chemistry (MOE), Nankai University, Tianjin, 300350, PR China
2Key Laboratory of Functional Polymer Materials of Ministry of Education, College of Chemistry, Nankai University, Tianjin, 300071, PR China
3Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300071, PR China
刊名: Microporous and Mesoporous Materials, 2020, Vol.293
来源数据库: Elsevier Journal
DOI: 10.1016/j.micromeso.2019.109821
关键词: Poly (acrylic acid)Mesoporous zeoliteIntracrystalline mesoporesTemplate
英文摘要: Abstract(#br)Many great efforts have been devoted to the synthesis of hierarchically zeolites due to their potentially significant technological applications for catalytic reactions involving bulky reactant/products. In this work, we report a facile hydrothermal route to prepare mesoporous silicalite-1 with plentiful intracrystalline mesopores (5–20 nm) using poly (acrylic acid) (PAA) as a mesoscale template. During the crystallization process, the PAA chains served as the space occupant for intracrystalline mesopores, meanwhile, a small amount of amphiphilic organosilane (dimethyloctadecyl-[3-(trimethoxysilyl)-propyl]-ammonium chloride, TPOAc) acted as auxiliary template to enhance the connection between the growing crystal domains and the PAA chains. After calcination, the mesopore...
全文获取路径: Elsevier  (合作)
影响因子:3.365 (2012)

  • zeolite 沸石
  • mesoscale 中等尺度
  • plentiful 大量的
  • synthesis 合成
  • template 模板