Metal-organic coordination polymer-derived carbon nanotubes: Preparation and application in detecting small molecules
金属-有机配位聚合物衍生碳纳米管:检测小分子的制备及应用
作者: Hong-Yan LinQian-Qian LiuYuan TianJian Luan
作者单位: 1College of Chemistry and Chemical Engineering, Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou 121013, PR China
2Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, PR China
刊名: Polyhedron, 2020, Vol.182
来源数据库: Elsevier Journal
DOI: 10.1016/j.poly.2020.114504
关键词: Metal-organic coordination polymerMulti-walled carbon nanotubesChemical vapor depositionFluorescent sensing property
英文摘要: Abstract(#br)Two new isostructural metal–organic coordination polymers (MOCPs) based on the bis-pyridyl-bis-amide ligand and thiophene dicarboxylic acid, namely [Cd(3-dpaa) 0.5 (2,5-TDC)(H 2 O) 2 ] ( 1 ) and [Zn(3-dpaa) 0.5 (2,5-TDC)(H 2 O) 2 ] ( 2 ) (3-dpaa = N , N′ -di(3-pyridyl)adipoamide and 2,5-H 2 TDC = 2,5-thiophenedicarboxylic acid), have been hydrothermally synthesized and structurally characterized. The fluorescent sensing behaviors of complex 2 have been studied. Moreover, complex 2 was used as a combined catalyst precursor to synthesize multi-walled carbon nanotubes (MWCNTs). The decomposition of ethylene in the presence of the Zn-MOCP by the chemical vapor deposition (CVD) method at 650 °C led to successful obtain as-grown MWCNT products. Interestingly, the as-grown MWCNTs...
全文获取路径: Elsevier  (合作)
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影响因子:1.813 (2012)

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关键词翻译
关键词翻译
  • coordination 配位
  • organic 有机的
  • carbon 
  • deposition 沉积
  • vapor 
  • property 所有权
  • detecting 检测
  • application 申请
  • polymer 聚合物
  • sensing 感觉