Combination of pure shift NMR and chemical shift selective filters for analysis of Fischer-Tropsch waste-water
将纯移位NMR和化学移位选择性滤池相结合用于费托废水分析
作者: Qi ZhaoYu LiuHui MaYan QiaoJianbin ChaoXianglin HouYuqi WangYingxiong Wang
作者单位: 1Shanxi Engineering Research Center of Biorefinery, Institute of Coal Chemistry, Chinese Academy of Sciences, 27 South Taoyuan Road, Taiyuan, 030001, PR China
2Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, PR China
3Department of Chemistry, Northern Michigan University, Marquette, MI, 49855, United States
4Research Institute of Applied Chemistry, Shanxi University, Taiyuan, 030006, PR China
刊名: Analytica Chimica Acta, 2020, Vol.1110 , pp.131-140
来源数据库: Elsevier Journal
DOI: 10.1016/j.aca.2020.03.014
关键词: Pure shift NMRZangger-sterkPSYCHETSE-PSYCHECSSF-TOCSYFischer-tropsch waste-water
英文摘要: Abstract(#br)Fischer-Tropsch (F-T) process is an important synthesis route to acquire clean liquid fuels through modern coal chemical industry, which converts syngas (CO and H 2 ) into hydrocarbon, and also generates oxygenates discharged as the F-T waste-water. These oxygen-containing compounds in F-T waste-water have the similar molecular weight and some are even isomers of each other. Hence, it is necessary to develop rapid and efficient analysis tools to obtain identification and quantitative information of the F-T waste-water. The pure shift NMR techniques provided only chemical shift information in one-dimension 1 H NMR spectra, without homonuclear J H-H coupling. In this work, we tested and compared three pure shift NMR techniques (including Zangger-Sterk, PSYCHE and TSE-PSYCHE...
全文获取路径: Elsevier  (合作)
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影响因子:4.387 (2012)

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关键词翻译
关键词翻译
  • selective 选择性的
  • shift 变位
  • water 
  • chemical 化学的
  • NMR N-Modular Redundancy
  • waste 岩屑
  • analysis 分析