Template free synthesis of hierarchical porous zeolite Beta with natural kaolin clay as alumina source
作者: Yuanyuan YueXiaoxue GuoTao LiuHaiyan LiuTinghai WangPei YuanHaibo ZhuZhengshuai BaiXiaojun Bao
作者单位: 1College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, PR China
2State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 102249, PR China
刊名: Microporous and Mesoporous Materials, 2020, Vol.293
来源数据库: Elsevier Journal
DOI: 10.1016/j.micromeso.2019.109772
关键词: Hierarchical zeoliteTemplate free synthesisNatural kaolin clayEsterificationZeolite beta
英文摘要: Abstract(#br)A template free synthesis route was developed for the synthesis of hierarchical zeolite Beta from a natural layered aluminosilicate mineral kaolin. Detailed study on the crystallization of zeolite Beta established the optimized synthesis condition, and the synthesized hierarchical Beta zeolite was fully studied by XRD, IR, SEM, TEM, BET, NH 3 -TPD, Py-IR and NMR techniques. The characterization results reveal that the hierarchical Beta zeolite possesses good crystallinity, bimodal pore architecture, large surface area, big pore volume, high acid site concentration and excellent hydrothermal stability. An improved catalytic performance was achieved in hierarchical Beta zeolite for the esterification of acetic acid with benzyl alcohol, and the high activity and selectivity in...
全文获取路径: Elsevier  (合作)
影响因子:3.365 (2012)

  • hierarchical 分级
  • Template 模板
  • Beta β
  • synthesis 合成
  • alumina 矾土
  • porous 多孔的
  • kaolin 高岭土
  • zeolite 沸石
  • source 
  • natural 自然的