An efficient and simple one-pot synthesis of 2-perfluoroalkylated benzo[1,3]dioxole derivatives via double–Michael reaction of fluorinated alkynes
作者: Guy Judicaël Ella NdongBadr JismySamuel Inack NgiMohamed Abarbri
作者单位: 1Laboratoire de Physico-Chimie des Matériaux et des Electrolytes pour l’Energie (PCM2E), EA 6299, Avenue Monge, Faculté des Sciences, Parc de Grandmont, 37200, Tours, France
2IKAMBA Organics, 39 rue des Granges Galands, 37550, Saint-Avertin, France
刊名: Journal of Fluorine Chemistry, 2018, Vol.212 , pp.45-50
来源数据库: Elsevier Journal
DOI: 10.1016/j.jfluchem.2018.05.005
关键词: Fluoroalkylated alkynesCatecholsDouble Michael-additionFluoroalkylated 13-benzodioxolesFluoroalkylated benzoxazolinesBenzothiazoline
原始语种摘要: Abstract(#br)An efficient, mild and very easy method for the synthesis of 2-fluoroalkylated 1,3-benzodioxole derivatives was developed through a double Michael-addition reaction on ethyl 4,4,4-trifluorobut-2-ynoate with corresponding catechols. The procedure does not require the use of expensive supplementary additives for the preparation of 2-fluoroalkylated benzo ketals.
全文获取路径: Elsevier  (合作)
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影响因子:1.939 (2012)

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关键词翻译
关键词翻译
  • reaction 反酌
  • derivatives 派生物
  • benzo 苯并
  • efficient 有用的
  • synthesis 合成
  • fluorinated 氟化的
  • dioxole 二恶茂
  • preparation 预备
  • corresponding 对应的
  • double 双重的