Absolute configuration of diterpenoids from Jatropha dioica by vibrational circular dichroism
作者: Eleuterio Burgueño-TapiaKatia Chávez-CastellanosErnestina Cedillo-PortugalPedro Joseph-Nathan
作者单位: 1Departamento de Química Orgánica, Escuela Nacional de Ciencias Biológicas, Instituto Politécnico Nacional, Prolongación de Carpio y Plan de Ayala, Col. Santo Tomás, Mexico City 11340, Mexico
2Departamento de Preparatoria Agrícola, Universidad Autónoma de Chapingo, Texcoco, Mexico 56230, Mexico
3Departamento de Química, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, Apartado 14-740, Mexico City 07000, Mexico
刊名: Tetrahedron: Asymmetry, 2017, Vol.28 (1), pp.166-174
来源数据库: Elsevier Journal
DOI: 10.1016/j.tetasy.2016.11.006
英文摘要: Abstract(#br)The absolute configuration of jatropholone A 1 and B 2 , including the possibility to observe the vibrational circular dichroism (VCD) capacity to differentiate between two epimeric compounds in the presence of an inherently dissymmetric chromophore, which normally dominates VCD and electronic circular dichroism (ECD) spectra, followed after comparison of their experimental and DFT calculated VCD spectra, allowed us to conclude that although non-local ( M / P ) chirality generated by atropisomerism dominates over local chirality generated by an ( R / S ) change, the stereogenic center can confidently be assigned by VCD after DFT calculations. In addition, the absolute configurations of jatrophatrione 3 and citlalitrione 4 , a compound proposed as a taxonomic marker for the...
全文获取路径: Elsevier  (合作)
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来源刊物:
影响因子:2.115 (2012)

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关键词翻译
关键词翻译
  • vibrational 振动的
  • configuration 配置
  • circular 循环的
  • dichroism 二色性