On the absolute configuration of 1-cyclopropylethan-1-amine
作者: Matthew W.D. PerryAnders ErikssonMarie Rydén Landergren
作者单位: 1RIA Medicinal Chemistry, Innovative Medicines and Early Development, AstraZeneca Gothenburg, Pepparedsleden, SE-431 83 Mölndal, Sweden
刊名: Tetrahedron: Asymmetry, 2017
来源数据库: Elsevier Journal
DOI: 10.1016/j.tetasy.2017.08.005
英文摘要: Abstract(#br)We observed a discrepancy between the reported specific rotation for the enantiomers of 1-cyclopropylethan-1-amine and the values for commercial material. Analyses by VCD of the free amine, by NMR analysis of the derived ( S )-O-methylmandelamides and an X-ray crystal structure of one of the mandelamides defined the specific rotation for each enantiomer.
全文获取路径: Elsevier  (合作)
影响因子:2.115 (2012)

  • configuration 配置
  • amine 
  • absolute 绝对的