3D phosphorus-carbon electrode with aligned nanochannels promise high-areal-capacity and cyclability in lithium-ion battery
作者: Yuhua YanHongyi XuChengxin PengPengcheng ZhangJunhe YangShiyou Zheng
作者单位: 1School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
2Shanghai Innovation Institute for Materials, Shanghai 200444, China
3State Key Laboratory of Advanced Chemical Power Sources, Guizhou Meiling Power Sources Co. Ltd., Zunyi, Guizhou 563003,China
刊名: Applied Surface Science, 2019, Vol.489 , pp.734-740
来源数据库: Elsevier Journal
DOI: 10.1016/j.apsusc.2019.05.329
关键词: Lithium ion batteryAnode materialsPhosphorusWood-derived carbonAligned microchannels
原始语种摘要: Abstract(#br)Despite of poor electrical conductivity and large volume expansion, low mass loading of phosphorus-based electrode severely decrease overall gravimetric/volumetric energy density, impeding its practical application in lithium ion batteries (LIBs). Herein, we construct a high-areal-capacity P@rGO-ACW electrode by warping phosphorus with rGO and confining in 3D microchanneled carbon matrix (P@rGO-ACW). The conductive 3D carbon scaffold (ACW) derived from natural wood acts as integrated porous current collector to accelerate the electrons/ions transport, while the vertical-alignment microchannels confine phosphorus and accommodate its volume expansion. The unique feature of phosphorus‑carbon electrode with 3D aligned nanochannels allows for a considerable improvement in...
全文获取路径: Elsevier  (合作)
影响因子:2.112 (2012)

  • battery 电池
  • lithium 
  • electrode 电极
  • carbon 
  • promise 允诺
  • capacity 电容量
  • phosphorus 
  • areal 
  • aligned 成一直线
  • derived 导生的