The preparation of electrophilic and electroneutral phosphane ligands and their substitution chemistry with Mo(CO) 6
作者: Natalia G. PetrochkoJaimee M. AshMichelle M. ChoateJustin SpottR. Peters
作者单位: 1Department of Chemistry, Wilkes University, 84 W. South St., Wilkes-Barre, PA 18766, USA
刊名: Inorganica Chimica Acta, 2013, Vol.402 , pp.116-122
来源数据库: Elsevier Journal
DOI: 10.1016/j.ica.2013.03.035
关键词: PhosphaneFluoroalkylphosphaneCoordination complexMolybdenum carbonyl complexesSecond order fluorine NMRAmino phosphanes
英文摘要: Abstract(#br)The synthesis, characterization and coordination chemistry of electroneutral and electron-poor phosphane ligands is reported. The addition of diaminochlorophosphanes [compounds of the type (R 2 N) 2 PCl] to ether solutions of C 2 F 5 Li produced the corresponding diaminopentafluoroethylphosphane compounds (R 2 N) 2 PC 2 F 5 (R 2 N=C 4 H 8 ON, 1 ; C 5 H 10 N, 2 ; and C 8 H 8 N, 3 ). Similar treatment of aminodichlorophosphanes with two equivalents of C 2 F 5 Li produced compounds of the type (R 2 N)P(C 2 F 5 ) 2 (R=C 4 H 8 ON, 4 ; C 5 H 10 N, 5 ; C 4 H 8 N, 6 ; and C 8 H 8 N, 7 ). These phosphanes were isolated as high boiling liquids (1, 2, 4–7) or as a solid ( 3 ) in moderate yields (44–71%)....
全文获取路径: Elsevier  (合作)
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影响因子:1.687 (2012)

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关键词翻译
关键词翻译
  • electrophilic 亲电的
  • CO Care Of
  • carbonyl 羰基
  • preparation 预备
  • fluorine 
  • electroneutral 电中性的
  • complex 超群
  • substitution 同位素置换
  • NMR N-Modular Redundancy
  • chemistry 化学