Highly soluble polynorbornene prepared by an anilinonaphthoquinone-ligated nickel complex via coordination-insertion polymerization
作者: Mitsuhiro OkadaYuushou NakayamaTakeshi Shiono
作者单位: 1Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Japan
刊名: Journal of Organometallic Chemistry, 2015, Vol.798 , pp.384-387
来源数据库: Elsevier Journal
DOI: 10.1016/j.jorganchem.2015.06.028
关键词: PolynorborneneVinyl-additionNickelSingle-site catalyst
英文摘要: Abstract(#br)Norbornene polymerization was conducted with 2-(2,6-diisopropylanilino)-1,4-naphthoquinone-ligated nickel complex ( 1 ) activated by B(C 6 F 5 ) 3 and dried modified methylaluminoxane (dMMAO) in toluene at 40 °C. The 1 -B(C 6 F 5 ) 3 system showed higher activity than the 1 -dMMAO system and gave higher molecular-weight polynorbornene via coordination-insertion polymerization. The solubility of the polymer obtained by 1 -B(C 6 F 5 ) 3 was also higher than that obtained by 1 -dMMAO, and dissolved in cyclohexane even at room temperature. The self-standing films of the polynorbornene obtained by the B(C 6 F 5 ) 3 system were prepared by the solution casting method with cyclohexane. The films thus prepared showed good transparency in the UV–visible region. The 13 C NMR spectra of...
全文获取路径: Elsevier  (合作)
影响因子:2 (2012)

  • coordination 配位
  • complex 超群
  • polymerization 聚合酌
  • nickel 
  • prepared 有准备的
  • soluble 可溶的
  • insertion 插入