Quantitative determination of butylated hydroxyanisole and n-propyl gallate in cosmetics using three-dimensional fluorescence coupled with second-order calibration
作者: Jian-Yao WangHai-Long WuYao ChenMin ZhaiXiang-Dong QingRu-Qin Yu
作者单位: 1State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
刊名: Talanta, 2013, Vol.116 , pp.347-353
来源数据库: Elsevier Journal
DOI: 10.1016/j.talanta.2013.05.028
关键词: Butylated hydroxyanisolePropyl gallateCosmetics samplesFluorescenceSecond-order calibrationSelf-weighted alternating normalized residue fitting (SWANRF)
原始语种摘要: Abstract(#br)This work presents a novel approach for simultaneous determination of butylated hydroxyanisole (BHA) and propyl gallate (PG) in a very interfering environment by combining the sensitivity of molecular fluorescence and the selectivity of the second-order calibration method. The excitation–emission fluorescence matrix data are processed by applying the second-order calibration method based on the self-weighted alternating normalized residue fitting (SWANRF) algorithm. The limits of detection (LOD) were 1.2–1.3ng/ml for BHA and 2.2–2.9ng/ml for PG. The recoveries from spiked cosmetics samples are in the ranges 95.7–103.9% for BHA and 95.9–105.7% for PG. The proposed method avoids preconcentration and elution procedures, so it considerably...
全文获取路径: Elsevier  (合作)
影响因子:3.498 (2012)

  • calibration 校准
  • cosmetics 整容术
  • fluorescence 荧光
  • gallate 没食子酸盐
  • dimensional 量纲的
  • butylated 丁基化的
  • determination 测定
  • second 
  • alternating 交替
  • normalized 校正的