Degradation of carbon tetrachloride in aqueous solution in the thermally activated persulfate system
作者: Minhui XuXiaogang GuShuguang LuZhaofu QiuQian SuiZhouwei MiaoXueke ZangXiaoliang Wu
作者单位: 1State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai 200237, China
刊名: Journal of Hazardous Materials, 2015, Vol.286 , pp.7-14
来源数据库: Elsevier Journal
DOI: 10.1016/j.jhazmat.2014.12.031
关键词: PersulfateCarbon tetrachlorideThermal activationSuperoxide radical anionGroundwater
原始语种摘要: Abstract(#br)Thermal activation of persulfate (PS) has been identified to be effective in the destruction of organic pollutants. The feasibility of carbon tetrachloride (CT) degradation in the thermally activated PS system was evaluated. The experimental results showed that CT could be readily degraded at 50°C with a PS concentration of 0.5M, and CT degradation and PS consumption followed the pseudo-first order kinetic model. Superoxide radical anion (O 2 − ) was the predominant radical species responsible for CT degradation and the split of CCl was proposed as the possible reaction pathways for CT degradation. The process of CT degradation was accelerated by higher PS dose and lower initial CT...
全文获取路径: Elsevier  (合作)
影响因子:3.925 (2012)

  • degradation 减嚣夷酌
  • aqueous 水的
  • solution 溶液
  • persulfate 过硫酸盐
  • tetrachloride 四氯化物
  • thermally 热地
  • initial 开首字母
  • effective 有效的
  • system 
  • carbon