Development of new iron catalysts for the tandem isomerization–aldol condensation of allylic alcohols
作者: Ramalinga UmaNicolas GouaultChristophe CrévisyRené Grée
作者单位: 1ENSCR, Laboratoire de Synthèses et Activations de Biomolécules, CNRS UMR 6052, Avenue du Général Leclerc, 35700 Rennes, France
刊名: Tetrahedron Letters, 2003, Vol.44 (33), pp.6187-6190
来源数据库: Elsevier Journal
DOI: 10.1016/S0040-4039(03)01556-9
原始语种摘要: Abstract(#br)(bda)Fe(CO) 3 and (COT)Fe(CO) 3 are shown to be excellent catalysts for the tandem isomerization–aldol reaction of allylic alcohols with aldehydes and to significantly increase the scope of this aldolization process, especially, in the case of sterically hindered aldehydes.
全文获取路径: Elsevier  (合作)
影响因子:2.397 (2012)

  • isomerization 异构化
  • allylic 烯丙基的
  • aldol 羟醛
  • alcohols 醇类
  • condensation 冷凝
  • aldehydes 
  • tandem 串联机
  • sterically 空间上
  • significantly 较大地
  • reaction 反酌