Spectral Faraday rotation in tripyridinium bis[tetrachloroferrate(III)] chloride molecular magnet at room temperature due to electronic transition
作者: M.B. FathiF. BaniasadiN. PanahiM.M. Tehranchi
作者单位: 1Department of Solid State, Faculty of Physics, Kharazmi University, Tehran, Iran
2Department of Physics, Shahid Beheshti University, Tehran, Iran
3Laser and Plasma Institute, Magnetophotonics Lab, Shahid Beheshti University, Tehran, Iran
刊名: Journal of Magnetism and Magnetic Materials, 2019, Vol.469 , pp.13-18
来源数据库: Elsevier Journal
DOI: 10.1016/j.jmmm.2018.08.022
关键词: Faraday rotationMolecular magnetElectronic transitionDFT
英文摘要: Abstract(#br)The physical mechanism responsible for Faraday rotation (FR) in magnetic molecules under the irradiation of visible light is under intense investigations. In this paper, a quantum mechanical description of the Faraday rotation is provided based on the electronic transitions between the molecular states. The method is applied on bis[tetrachloroferrate(III)]chloride magnetic molecule showing significant FR under irradiation of the visible light ( λ = [ 450 , 775 ] nm ) at room temperature. Use of dielectric tensor for the molecule in terms of oscillator strengths between HOMOs (highest occupied molecular orbital) and LUMOs (lowest unoccupied molecular orbital) leads to magnetization curve as a function of frequency. The results are obtained in view...
全文获取路径: Elsevier  (合作)
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影响因子:1.826 (2012)

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关键词翻译
关键词翻译
  • transition 转移
  • rotation 旋转
  • Faraday 法拉第
  • magnet 磁铁
  • temperature 温度
  • electronic 电子的
  • chloride 氯化物
  • molecular 分子的
  • DFT Diagnostic Function Test