Bis(μ-chloro) bridged 1D Cu I and Cu II coordination polymer complex and mononuclear Cu II complex: Synthesis, crystal structure and biological properties
作者: Thangavel ThirunavukkarasuHazel A. SparkesC. BalachandranS. AwaleKaruppannan NatarajanV.G. Gnanasoundari
作者单位: 1Department of Chemistry, CBM College, Coimbatore 641042, India
2Department of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK
3Division of Natural Drug Discovery, Institute of Natural Medicine, University of Toyama, 2630 Sugitani, Toyama 930-0194, Japan
4Department of Chemistry, Bharathiar University, Coimbatore 641042, India
刊名: Journal of Photochemistry & Photobiology, B: Biology, 2018, Vol.181 , pp.59-69
来源数据库: Elsevier Journal
DOI: 10.1016/j.jphotobiol.2018.02.013
关键词: Schiff base ligandsPolymer and mononuclear Cu(II) complexesDNA/BSA bindingCytotoxicity
原始语种摘要: Abstract(#br)A novel one-dimensional coordination polymer containing Cu(I)Cu(II) core with chloro bridge on Cu(I) and ligand bridge on Cu(II) ions ( 1 ) and a mononuclear Cu(II) complex ( 2 ) have been synthesized from the reactions of 3- and 4-methoxy-3-quinolin-3-ylimino-methyl-2-phenol with [CuCl 2 (PPh 3 ) 2 ]. The ligands and the complexes have been characterized by spectral and analytical methods. In addition, the structures of both the ligands and the copper complexes were confirmed by single crystal X-ray diffraction studies. In both complexes, the phenolic oxygen and azomethine nitrogen atom of the ligand coordinate to the copper ions in a monobasic bidentate manner resulting in an approximately square planar...
全文获取路径: Elsevier  (合作)

  • complex 超群
  • chloro 绿
  • coordination 配位
  • crystal 晶体
  • properties 道具
  • mononuclear 单核的
  • bridged 跨接的
  • biological 生物学的
  • structure 构造
  • polymer 聚合物