Gold-catalyzed synthesis of enantioenriched furfurylamines from amino acids
作者: Benjamin GuieuMyriam Le RochMichèle DavidNicolas Gouault
作者单位: 1Equipe PNSCM, UMR 6226, Université de Rennes 1, 2 avenue du Pr. Léon Bernard, 35043 Rennes Cedex, France
刊名: Tetrahedron: Asymmetry, 2015, Vol.26 (15-16), pp.868-875
来源数据库: Elsevier Journal
DOI: 10.1016/j.tetasy.2015.06.014
英文摘要: Abstract(#br)A convenient gold-catalyzed asymmetric synthesis of polysubstituted furfurylamines starting from amino acids has been achieved. The cyclization proceeded under mild conditions and generally provided the furan or iodofuran derivatives in good to excellent yields and with high enantiomeric excess. Iodofurans were validated as good intermediates for classical organometallic coupling reactions.
全文获取路径: Elsevier  (合作)
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影响因子:2.115 (2012)

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关键词翻译
关键词翻译
  • catalyzed 催化的
  • amino 氨基
  • synthesis 合成