Synthetic and structural studies of heteroleptic platinum(II) and palladium(II) complexes containing thiacrown and monodentate phosphane ligands
作者: Trevor P. LatendresseSteven J. AdamsGregory J. GrantJohn P. LeeAllen G. Oliver
作者单位: 1Department of Chemistry, The University of Tennessee at Chattanooga, United States
2Department of Chemistry, The University of Notre Dame, United States
刊名: Polyhedron, 2016, Vol.114 , pp.80-87
来源数据库: Elsevier Journal
DOI: 10.1016/j.poly.2015.10.037
关键词: Thioether complexesPlatinum complexesPalladium complexesPlatinum nuclear magnetic resonancePhosphane complexes
原始语种摘要: Abstract(#br)We wish to report the syntheses, spectroscopic, and structural properties for six new Pt(II) and Pd(II) heteroleptic complexes containing the monodentate phosphane ligands PTA (1,3,5-triaza-7-phosphaadamantane) or PMe 3 (trimethylphosphane) and the crown trithioether [9]aneS 3 (1,4,7-trithiacyclononane). All six reported complexes have the general formula [M([9]aneS 3 )(P 2 )](PF 6 ) 2 or [M([9]aneS 3 )(P)(Cl)](PF 6 ) where M=Pt(II) or Pd(II) and P is the monodentate phosphane ligand. All six complexes form similar structures in which the metal center is surrounded by two sulfur atoms from the trithioether ligand and a cis arrangement of either the two phosphorus donors or the chlorido and phosphorus donor. The third sulfur from the...
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影响因子:1.813 (2012)

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关键词翻译
关键词翻译
  • 磁的 构造
  • palladium 
  • complexes 联合企业
  • II Interactive Interface
  • monodentate 单原子螯合配体
  • Palladium 智慧女神雅典娜的神像
  • platinum 
  • resonance 共振
  • structural 构造
  • magnetic 构造
  • containing 包含的