Electrophilic carbon transfer in gold catalysis: synthesis of substituted chromones
作者: Jacques RenaultZhao QianPhilippe UriacNicolas Gouault
作者单位: 1Université de Rennes 1, UMR 6226 Sciences Chimiques de Rennes, Equipe PNSCM, UFR Sciences Biologiques et Pharmaceutiques, 2, Av., du Pr. Léon Bernard, 35043 Rennes Cedex, France
刊名: Tetrahedron Letters, 2011, Vol.52 (19), pp.2476-2479
来源数据库: Elsevier Journal
DOI: 10.1016/j.tetlet.2011.03.018
关键词: ChromonesGold catalysisElectrophilic transferIsomerisation
英文摘要: Abstract(#br)Using easily accessible aromatic alkoxy-arylalkynones, we have investigated the gold-catalyzed intramolecular addition of ethers to alkynes, to give easy access to various substituted chromones. This reaction involves the transfer of the ether substituent via a carbodemetallation process. We also noticed a competing isomerization of several starting materials for which we propose a second gold catalyzed mechanism.
全文获取路径: Elsevier  (合作)
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影响因子:2.397 (2012)

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关键词翻译
关键词翻译
  • catalysis 催化
  • substituted 取代的
  • chromones 色酮
  • carbon 
  • transfer 转换
  • synthesis 合成