Silver (I) poly(1,2,4-triazolyl)borate complexes containing monodentate phosphane ligands
作者: Giancarlo Gioia LobbiaMaura PelleiClaudio PettinariCarlo SantiniBrian W. SkeltonAllan H. White
作者单位: 1Dipartimento di Scienze Chimiche, Università degli Studi di Camerino, via S. Agostino 1, 62032 Camerino MC, Italy
2Chemistry M313, The University of Western Australia, Crawley, WA 6009, Australia
刊名: Inorganica Chimica Acta, 2004, Vol.358 (4), pp.1162-1170
来源数据库: Elsevier Journal
DOI: 10.1016/j.ica.2004.11.023
关键词: Scorpionate ligandsTriazoleSilverPhosphane ligandsX-ray crystal structure
英文摘要: Abstract(#br)New silver (I) derivatives containing monodentate tertiary phosphanes and anionic poly(triazol-1-yl)borate ligands have been prepared from the reaction of AgNO 3 and PR 3 (R=Ph, Bn, o -tolyl, m -tolyl, p -tolyl) and potassium dihydrobis(1,2,4-triazolyl)borate, K[H 2 B(tz) 2 ], or potassium hydrotris(1,2,4-triazolyl)borate, K[HB(tz) 3 ]; their solid state and solution properties have been investigated through analytical and spectroscopic measurements (IR, 1 H-, and 31 P NMR). The 1 H- and 31 P NMR solution spectra in some cases can be interpreted on the basis of a dissociation of [{H 2 B(tz) 2 }Ag(PR 3 ) 2 ] into [{H 2 B(tz) 2 }Ag(PR 3 )] and PR 3 . All the compounds are soluble in chlorinated solvents and are non-electrolytes in CH 2 Cl 2...
全文获取路径: Elsevier  (合作)
影响因子:1.687 (2012)

  • Silver 
  • triazolyl 三唑基
  • poly 
  • monodentate 单原子螯合配体
  • complexes 联合企业
  • borate 硼酸盐
  • structure 构造
  • crystal 晶体
  • containing 包含的