Electrochemical Behavior of Iron(III)/Iron(II) Couple in Dimethylformamide
作者: A. SafaviL. Fotouhi
作者单位: 1Department of Chemistry, College of Sciences, Shiraz University, Shiraz, Iran
刊名: Microchemical Journal, 1998, Vol.60 (3), pp.224-230
来源数据库: Elsevier Journal
DOI: 10.1006/mchj.1998.1664
原始语种摘要: Abstract(#br)The electrochemical behavior of the iron(III)/iron(II) couple was investigated in both complexing (Cl − ) and noncomplexing (ClO − 4 ) media in dimethylformamide (DMF), and the results were compared with the results obtained in aqueous solutions. The diffusion coefficients for iron(III) and iron(II) in DMF are larger in complexing medium than in noncomplexing medium, contrary to the results obtained in aqueous solutions. The heterogeneous electron transfer rate constants for the iron(III)/iron(II) couple obtained in DMF were found to be smaller in DMF solution as a result of the specific adsorption of DMF. The formal potential of the Fe(III)/Fe(II) couple in DMF is about 0.2 V less positive in noncomplexing medium as a result of the greater stabilization of iron(III) by the...
全文获取路径: Elsevier  (合作)
影响因子:2.879 (2012)

  • solution 溶液
  • aqueous 水的
  • result 成果
  • couple 电偶
  • complexing 配合
  • chemical 化学的
  • DMF Disc Management Facility
  • adsorption 吸附
  • formal 形式的
  • potential