4,4-Bipyridinium ionic liquids exhibiting excellent solubility for metal salts: Potential solvents for electrodeposition
作者: Atakilt AbebeShimelis AdmassieIgnacio J. Villar-GarciaYonas Chebude
作者单位: 1Chemistry Department, Faculty of Chemical and Physical Sciences, College of Natural Sciences, Addis Ababa University, P.O. BOX 1176, Addis Ababa, Ethiopia
刊名: Inorganic Chemistry Communications, 2013, Vol.29 , pp.210-212
来源数据库: Elsevier Journal
DOI: 10.1016/j.inoche.2012.11.034
关键词: Ionic liquidsMetal saltsBipyridiniumBipyridineElectrodepositionMetal extraction
原始语种摘要: Abstract(#br)Newly synthesised 4,4-bipyridinium based ionic liquids exhibit good metal coordinating abilities and are able to dissolve metal salts at high concentrations. The ability to capture metal salts into the ionic liquid media facilitates the application of ionic liquids in many areas such as metal extraction or electrochemistry. The ionic liquid n-butyl-4,4-bipyridinium bis(trifluoromethyl)sulfonylamide ([C 4 Bipyr][Tf 2 N]) exhibits a large liquidus range and a wide electrochemical window. The successful electrodeposition of Cu (II) to Cu (0) from a solution of Cu(NO 3 ) 2 in [C 4 Bipyr][Tf 2 N] shows the potential of this new type of ionic liquids for electrodeposition.
全文获取路径: Elsevier  (合作)
影响因子:2.016 (2012)

  • liquids 液体
  • ionic 离子的
  • salts 盐类
  • solubility 溶度
  • metal 金属
  • extraction 提取
  • coordinating 协调
  • butyl 丁基
  • dissolve 溶解
  • excellent 优秀的