Reinforcement of an ionic thermoplastic elastomer based on a zinc-sulfonated ethylene-propylene-diene terpolymer by precipitated silica
作者: Thomas KurianD. KhastgirP.P. DeD.K. TripathyS.K. De
作者单位: 1Rubber Technology Centre, Indian Institute of Technology, Kharagpur 721302, India
刊名: Polymer, 1996, Vol.37 (25), pp.5597-5605
来源数据库: Elsevier Journal
DOI: 10.1016/S0032-3861(96)00392-8
关键词: ionic thermoplastic elastomerprecipitated silicareinforcement
原始语种摘要: Abstract(#br)Precipitated silica improves the physical properties of a zinc-sulfonated ethylene-propylene-diene terpolymer (SEPDM) of high (i.e. 75 wt%) ethylene content. The properties studied include hardness, stress-strain characteristics, tear strength, abrasion resistance and hysteresis. Processability studies carried out by using the Monsanto Processability Tester (MPT) show that silica increases the melt viscosity of the zinc-sulfonated EPDM. Results obtained from dynamic mechanical analysis (d.m.a.) show that silica reinforces the backbone chain and weakens the ionic associations. The results obtained from dielectric thermal analysis (d.e.t.a.) confirm the d.m.a. results and suggest that the formation of multiplets and clusters present in the SEPDM are adversely affected by silica.
全文获取路径: Elsevier  (合作)
影响因子:3.379 (2012)

  • silica 硅土
  • sulfonated 磺化
  • elastomer 弹性体
  • ionic 离子的
  • thermoplastic 热塑性塑料
  • terpolymer 三元共聚物
  • diene 二烯
  • ethylene 乙烯
  • abrasion 海蚀
  • hardness 硬度