Visible light-promoted metal-free aerobic oxyphosphorylation of olefins: A facile approach to β -ketophosphine oxides
作者: Yun ShiRongshun ChenKang GuoFei MengShujun CaoChen GuYingguang Zhu
作者单位: 1Jiangsu Key Laboratory of Pesticide Science and Department of Chemistry, College of Sciences, Nanjing Agricultural University, Nanjing 210095, China
2College of Plant Protection, Nanjing Agricultural University, Nanjing 210095, China
3Department of Pharmacy, Jiangsu Vocational College of Medicine, Yancheng 224005, China
刊名: Tetrahedron Letters, 2018, Vol.59 (21), pp.2062-2065
来源数据库: Elsevier Journal
DOI: 10.1016/j.tetlet.2018.04.040
关键词: Visible lightPhotoredox catalysisOxyphosphorylationAlkenesΒ -Ketophosphine oxides
英文摘要: Abstract(#br)A metal-free direct aerobic oxyphosphorylation of alkenes with H -phosphine oxides has been developed utilizing visible light photoredox catalysis. A variety of β -ketophosphine oxides have been obtained in good yields from simple olefins under air with inexpensive rhodamine B as the non-metallic photocatalyst. This method provides a mild, green, and practical synthetic approach to valuable β -ketophosphine oxides.
全文获取路径: Elsevier  (合作)
影响因子:2.397 (2012)

  • facile 容易的
  • catalysis 催化
  • aerobic 需氧的
  • light 
  • metal 金属
  • approach