Synthesis of perfluoroalkylnitroborates: structure of Cs[(C 2 F 5 ) 3 BNO 2 ]
作者: David J. BrauerYonas ChebudeGottfried Pawelke
作者单位: 1Anorganische Chemie, FB9, Universität-Gesamthochschule, D-42097 Wuppertal, Germany
2Department of Chemistry, Addis Ababa University, POB 1176, Addis Ababa, Ethiopia
刊名: Journal of Fluorine Chemistry, 2001, Vol.112 (2), pp.265-270
来源数据库: Elsevier Journal
DOI: 10.1016/S0022-1139(01)00511-5
关键词: BoronPerfluoroalkyl groupCrystal structure
原始语种摘要: Abstract(#br)(CF 3 ) 2 BNMe 2 reacts with CF 3 (CF 2 ) n I/tetrakisdimethylaminoethylene (TDAE) to form the dimethylamine boranes CF 3 (CF 2 ) n (CF 3 ) 2 B·NHMe 2 ( n =1 ( 2 ), 3 ( 3 )). Reacting C 2 F 5 I with Br 2 BNMe 2 and TDAE, (C 2 F 5 ) 3 B·NHMe 2 ( 4 ) was obtained in low yield. Compounds 2 – 4 react with ozone in CsOH solution to form the corresponding nitroborates(#br)Cs[CF 3 (CF 2 ) n (CF 3 ) 2 BNO 2 ] ( 2a ), ( 3a ) and Cs[(C 2 F 5 ) 3 BNO 2 ] (4a) . The structure of 4a has been determined by X-ray diffraction.
全文获取路径: Elsevier  (合作)
分享到:
来源刊物:
影响因子:1.939 (2012)

×
关键词翻译
关键词翻译
  • dimethylamine 二甲胺
  • corresponding 对应的
  • solution 溶液
  • ozone 臭氧
  • structure 构造
  • boranes 硼烷
  • diffraction 衍射
  • react 反应
  • yield 成品率