Reductive silylation of gem -difluorinated phosphonium salts
作者: Artem V. TsymbalVitalij V. LevinMarina I. StruchkovaVladimir A. KokorekinAlexander A. KorlyukovAlexander D. Dilman
作者单位: 1N. D. Zelinsky Institute of Organic Chemistry, 119991, Moscow, Leninsky prosp. 47, Russian Federation
2M. V. Lomonosov Moscow State University, Department of Chemistry, 119991, Moscow, Leninskie Gory 1-3, Russian Federation
3I. M. Sechenov First Moscow State Medical University, 119991, Moscow, Trubetskaya st. 8-2, Russian Federation
4A. N. Nesmeyanov Institute of Organoelement Compounds, 119991, Moscow, Vavilov str. 28, Russian Federation
5N. I. Pirogov Russian National Research Medical University, Ostrovitianov str., 1, 117997, Moscow, Russian Federation
刊名: Journal of Fluorine Chemistry, 2018, Vol.205 , pp.58-61
来源数据库: Elsevier Journal
DOI: 10.1016/j.jfluchem.2017.11.009
关键词: Difluorinated compoundsPhosphonium saltsSilicon reagentsReductive silylation
原始语种摘要: Abstract(#br)gem -Difluorinated phosphonium salts, generated from aldehydes and difluorinated phosphobetaine reagent, were converted into corresponding silicon reagents. The reductive silylation of carbon-phosphorus bond is carried out using a combination of magnesium and chlorotrimethylsilane in dimethylformamide. For a model difluoroined phosphonium salt, X-ray structure and reduction potential are provided.
全文获取路径: Elsevier  (合作)
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来源刊物:
影响因子:1.939 (2012)

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关键词翻译
关键词翻译
  • silylation 硅烷化
  • phosphonium 膦根
  • salts 盐类
  • aldehydes 
  • converted 转[变]换
  • compounds 化合物
  • phosphorus 
  • corresponding 对应的
  • reductive 减少的
  • potential