Synthesis, characterization, and coordination chemistry of several novel electroneutral phosphane ligands
作者: Michelle M. ChoateRussell G. BaughmanJennifer E. PhelpsR. Gregory Peters
作者单位: 1Department of Chemistry, Wilkes University, 84 W. South St., Wilkes-Barre, PA 18766, USA
2Department of Chemistry, Truman State University, Kirksville, MO 63501, USA
3Department of Chemistry, University of Memphis, Memphis, TN 38152, USA
刊名: Journal of Organometallic Chemistry, 2010, Vol.696 (4), pp.956-962
来源数据库: Elsevier Journal
DOI: 10.1016/j.jorganchem.2010.10.038
关键词: PhosphaneFluoroalkylphosphaneCoordination complexMolybdenumAmino phosphaneFluorovinyl phosphanes
原始语种摘要: Abstract(#br)The reaction of fluorocarbon (R f ) reagents C 2 F 5 Li or C 2 F 3 Li with diaminochlorophosphanes (R 2 N) 2 PCl produced four new phosphane ligands of the type (R 2 N) 2 P(R f ). Addition of (Et 2 N) 2 PCl to ethereal solutions of C 2 F 5 Li or C 2 F 3 Li produced (Et 2 N) 2 PC 2 F 5 1 and (Et 2 N) 2 PC 2 F 3 2 ; treatment of (C 4 H 4 N) 2 PCl and (C 4 H 8 N) 2 PCl with C 2 F 5 Li afforded (C 4 H 4 N) 2 PC 2 F 5 3 and (C 4 H 8 N) 2 PC 2 F 5 4 . All ligands were isolated as colorless, high-boiling liquids. Substitution reactions of 1 – 4 with Mo(CO) 6 in a refluxing alkane solvent yielded complexes of the type (L)Mo(CO) 5 (L = (Et 2 N) 2 PC 2 F 5 , 5 ; (Et 2 N) 2 PC 2 F 3 6 ; (C 4 H 4 N) 2 PC 2 F 5 7 and (C 4 H 8 N) 2 PC 2 F 5 8 ) as colorless solids in low to moderate...
全文获取路径: Elsevier  (合作)
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影响因子:2 (2012)

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关键词翻译
关键词翻译
  • electroneutral 电中性的
  • coordination 配位
  • several 各自
  • novel 长篇小说
  • chemistry 化学