Synthesis of 3-substituted indolizidines from amino-ynones derivatives
作者: Huy-Dinh VuJacques RenaultThierry RoisnelNicolas GouaultPhilippe Uriac
作者单位: 1Produits Naturels, Synthèse et Chimie Médicinale, UMR 6226, Institut des Sciences Chimiques de Rennes, Université de Rennes 1, 2, Avenue du Pr Léon Bernard, 35043 Rennes Cedex, France
2Department of Chemistry, Vietnam Forestry University, Hanoi, Viet Nam
3Institut des Sciences Chimiques de Rennes, Centre de Diffractométrie X, UMR 6226 CNRS-Université de Rennes 1, F-35042 Rennes Cedex, France
刊名: Tetrahedron Letters, 2016, Vol.57 (27-28), pp.3036-3038
来源数据库: Elsevier Journal
DOI: 10.1016/j.tetlet.2016.05.108
关键词: Amino-ynoneIndolizidineMethanesulfonic acidZinc chloride
英文摘要: Abstract(#br)Two types of indolizidine derivatives can be synthesized from amino-ynones. In the presence of methanesulfonic acid, Meyer–Schuster rearrangement furnished vinylogues of indolizidin-3-ones whereas treatment with zinc chloride gave stable 3-alkynyl-1,5,6,7,8,8 a -hexahydroindolizine-zinc complexes that were reduced to 3-alkynylindolizidines.
全文获取路径: Elsevier  (合作)
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影响因子:2.397 (2012)

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关键词翻译
关键词翻译
  • substituted 取代的
  • derivatives 派生物
  • chloride 氯化物
  • amino 氨基