The effect of flow-field structure in toluene hydrogenation electrolyzer for energy carrier synthesis system
作者: Kensaku NagasawaAkihiro KatoYoshinori NishikiYoshimasa MatsumuraMahito AtobeShigenori Mitsushima
作者单位: 1Green Hydrogen Research Center, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
2De Nora Permelec Limited, 2023-15 Endo, Fujisawa 252-0816, Japan
3Department of Environment and System Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
4Institute of Advanced Sciences, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
刊名: Electrochimica Acta, 2017, Vol.246 , pp.459-465
来源数据库: Elsevier Journal
DOI: 10.1016/j.electacta.2017.06.081
关键词: Toluene/methylcyclohexane organic hydrideHydrogenation electrolysisFlow-field structure
原始语种摘要: Abstract(#br)In this study, we investigated the effect of the design of the cathode flow-field structure on the electrochemical performance of the electrolyzer for the toluene-methylcyclohexane electrocatalytic hydrogenation synthesis system. The patterns of the basic flow-fields; i.e. parallel, interdigit, serpentine and porous-carbon, were investigated based on linear sweep voltammetry (LSV), internal, and cathodic and anodic charge transfer resistances with impedance spectroscopy and current efficiency. The flow-field pattern affected the toluene mass transportation and H 2 gas generation as a side reaction. Based on the LSV curve, the porous-carbon did not affect the overvoltage for the decrease in the toluene concentration, and showed the lowest cell voltage in the all flow-fields....
全文获取路径: Elsevier  (合作)
影响因子:3.777 (2012)

  • toluene 甲苯
  • hydrogenation 加氢
  • structure 构造
  • electrolyzer 电解槽
  • field 
  • synthesis 合成
  • effect 效应
  • porous 多孔的
  • carbon 
  • concentration 浓度