Catalytic Hydrotreatment of the Pyrolytic Sugar and Pyrolytic Lignin Fractions of Fast Pyrolysis Liquids Using Nickel Based Catalysts
作者: Wang YinMaria V. Alekseeva (Bykova)Robertus Hendrikus VenderboschVadim A. YakovlevHero Jan Heeres
作者单位: 1Department of Chemical Engineering, ENTEG, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands;
2Boreskov Institute of Catalysis, Akademika Lavrentieva Prospekt, 5, 630090 Novosibirsk, Russia; (M.V.A.(B.)); (V.A.Y.)
3Novosibirsk State University, Pirogova Street, 2, 630090 Novosibirsk, Russia
4Biomass Technology Group BV, Josink Esweg 34, 7545 PN Enschede, The Netherlands;
刊名: Energies, 2020, Vol.13 (1)
来源数据库: Multidisciplinary Digital Publishing Institute
DOI: 10.3390/en13010285
关键词: Pyrolysis liquidsPyrolytic sugarsPyrolytic ligninNickel-based catalystsCatalytic hydrotreatment
原始语种摘要: Catalytic hydrotreatment is recognized as an efficient method to improve the properties of pyrolysis liquids (PO) to allow co-feeding with fossil fuels in conventional refinery units. The promising catalyst recipes identified so far are catalysts with high nickel contents (38 to 57 wt.%), promoted by Cu, Pd, Mo and/or a combination, and supported by SiO2, SiO2-ZrO2, SiO2-ZrO2-La2O3 or SiO2-Al2O3. To gain insights into the reactivity of the pyrolytic sugar (PS) and pyrolytic lignin (PL) fraction of PO, hydrotreatment studies (350 °C, 120 bar H2 pressure (RT) for 4 h) were performed in a batch autoclave. Catalyst performance was evaluated by considering the product properties (H/C ratio, the charring tendency (TGA) and molecular weight distribution (GPC)) and the results were compared with...
全文获取路径: MDPI 

  • hydrotreatment 加氢处理
  • catalyst 催化剂
  • fraction 分数
  • monometallic 单本位制
  • supported 支承的
  • autoclave 压热器高压锅
  • bimetallic 双金属的
  • liquids 液体
  • elemental 元素的
  • sugars