Transmetallation of β-allenyl silanes: efficient synthesis of dienyl chlorostannanes and chlorostibines
作者: Mokhtar LahrechJérôme ThibonnetSalih HaciniMaurice Santelli Jean-Luc Parrain
刊名: Chem. Commun., 2002, Vol.0 , pp.644-645
来源数据库: Royal Society of Chemistry
DOI: 10.1039/B111580B
原始语种摘要: The reaction of 1-trimethylsilylbuta-2,3-diene with tin tetrachloride, antimony trichloride or antimony pentachloride gave the corresponding buta-1,3-dien-2-yl halostannane or stibine derivatives; this ligand exchange was extended to other β-allenylsilanes.
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关键词翻译
关键词翻译
  • stibine 锑化氢
  • pentachloride 五氯化物
  • tetrachloride 四氯化物
  • antimony 
  • efficient 有用的
  • synthesis 合成
  • reaction 反酌
  • derivatives 派生物
  • diene 二烯
  • extended 扩展