Poly[bis(acetone-&kappa;O)bis{&mu; 3 -1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-&kappa;<sup>4</sup>O:O,O&prime;:O&prime;}sodium(I)chromium(III)]
作者: Shinpei ItoYohei SatoJin Mizuguchi
作者单位: 1Department of Applied Physics, Faculty of Engineering, Yokohama National University, Tokiwadai 79-5, Hodogaya-ku, Yokohama 240-8501, Japan
2Department of Applied Physics, Graduate School of Engineering, Yokohama National University, Tokiwadai 79-5, Hodogaya-ku, Yokohama 240-8501, Japan
刊名: Acta Crystallogr E Struct Rep Online, 2008, Vol.64 (Pt 2), pp.m333-m334
来源数据库: International Union of Crystallography
DOI: 10.1107/S1600536808000433
原始语种摘要: The title compound, [CrNa(C 16 H 9 ClN 2 O 2 ) 2 (C 3 H 6 O) 2 ] n , is an azo-CrIII complex polymer that is used as a charge-control agent in electrophotography. The monomeric unit is composed of octahedral CrIII and NaI units, and is characterized by twofold rotation symmetry. The CrIII atom is chelated by two N and four O atoms from two [(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The ligand anion exists in the cis form. The NaI atom is coordinated by two phenoxy O atoms from a neighboring CrIII unit, two naphthoxy O atoms from another neighboring CrIII unit and two O atoms from acetone molecules. The dinuclear complex forms a one-dimensional polymer running along the c axis.
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影响因子:0.347 (2011)

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关键词翻译
关键词翻译
  • acetone 丙酮
  • chloro 绿
  • sodium 
  • mu 甲撑单元
  • naphtholate 萘酚盐
  • neighboring 邻近
  • phenoxy 苯氧基
  • octahedral 八面体
  • polymer 聚合物
  • anion 阴离子