ChemInform Abstract: Copper‐Catalyzed Cross‐Coupling of Fluorinated Vinylstannanes with Organic Halides.
作者: Khalid ZineJulien PetrignetPierre‐Olivier DelayeYvan CarcenacJean‐Luc ParrainMohamed Abarbri
作者单位: 1Lab. Infect. Sante Publique, Fac. Sci. Tech., Univ. Francois‐Rabelais, F‐37200 Tours, Fr.
刊名: ChemInform, 2016, Vol.47 (26),
来源数据库: Wiley Journal
DOI: 10.1002/chin.201626069
关键词: reactions of organo‐metal compoundsC‐C bond formatione/z‐selectivity (incl. e/z‐isomerism)halogen compounds (acyclic compounds)
原始语种摘要: Abstract(#br)The Cu‐catalyzed cross‐coupling of β‐stannylated alkenoate (I) having a trifluoromethyl group with a variety of organyl bromides and iodides is presented to give 3‐substituted‐3‐trifluoromethylacrylates with a clean olefinic configuration.
全文获取路径: Wiley  (合作)

  • selectivity 选择性
  • isomerism 异构
  • catalyzed 催化的
  • iodides 碘化物
  • compounds 化合物
  • halogen 卤素
  • substituted 取代的
  • acyclic 非周期的
  • coupling 连接
  • organo 有机的