Novel Elastically Stretchable Metal–Organic Framework Laden Hydrogel with Pearl–Net Microstructure and Freezing Resistance through Post‐Synthetic Polymerization
作者: Jun XuCongyi WuYue QiuXing TangDawen Zeng
作者单位: 1School of Materials Science and Engineering State Key Laboratory of Materials Processing and Die Mould Technology Huazhong University of Science and Technology (HUST) 1037 Luoyu Street Wuhan 430074 P. R. China
刊名: Macromolecular Rapid Communications, 2020, Vol.41 (6), pp.n/a-n/a
来源数据库: Wiley Journal
DOI: 10.1002/marc.201900573
关键词: ElasticallyFreezing resistanceMetal–organic framework laden hydrogelsPearl–net microstructuresPost‐synthetic polymerization
原始语种摘要: Abstract(#br)Nanocomposite hydrogels (NCs) with mechanical properties suitable for a diverse range of applications can be made by combining polymer hydrogel networks with various inorganic nanoparticles. However, the mechanical properties and functions of conventional NCs are seriously limited by the poor structural or functional tunability of common nanofillers and by the low amounts of such fillers that can be added. Here, the fabrication of novel elastically stretchable and compressible nanocomposite hydrogels (MIL‐101‐MAAm/PAAm) with a distinctive pearl–net microstructure and a metal–organic framework (MOF) content in the range of 20–60 wt% through post‐synthetic polymerization (PSP) is reported. The MOFs, which are compatible with polymers and have a high degree of modifiability in...
全文获取路径: Wiley  (合作)

  • polymerization 聚合酌
  • tensile 拉的
  • modifiability 可修改性
  • framework 构架
  • preparing 预梳
  • fabrication 制造
  • synthetic 合成的
  • organic 有机的
  • properties 道具
  • microstructure 微结构