ChemInform Abstract: Sequential 1,4‐/1,2‐Addition of Lithium(trimethylsilyl)diazomethane onto Cyclic Enones to Induce C—C Fragmentation and N—Li Insertion.
作者: Matthew J. O'ConnorChunrui SunXinyu GuanVenkata R. SabbasaniDaesung Lee
作者单位: 1Dep. Chem., Univ. Ill., Chicago, IL 60607, USA
刊名: ChemInform, 2016, Vol.47 (25),
来源数据库: Wiley Journal
DOI: 10.1002/chin.201625050
关键词: reactions of organo‐metal compoundsinsertion reactionsring opening reactionsring closure reactionsannulation reactionspyrazole derivativesdiazepine derivatives
原始语种摘要: Abstract(#br)Cyclic α,β‐unsaturated ketones undergo double additions with lithium(trimethylsilyl)diazomethane, effectively generating various molecular frameworks with complexity and diversity.
全文获取路径: Wiley  (合作)

  • diazomethane 重氮甲烷
  • unsaturated 未饱和的
  • pyrazole 吡唑
  • annulation 
  • derivatives 派生物
  • organo 有机的
  • diazepine 二氮杂草
  • compounds 化合物
  • closure 闭合
  • opening 开口