ChemInform Abstract: Pd‐Catalyzed Regioselective Activation of gem‐Difluorinated Cyclopropanes: A Highly Efficient Approach to 2‐Fluorinated Allylic Scaffolds.
作者: Jun XuEbrahim‐Alkhalil AhmedBin XiaoQian‐Qian LuYun‐Long WangChu‐Guo YuYao Fu
作者单位: 1Dep. Chem., Univ. Sci. Technol. China, Hefei 230026, Peop. Rep. China
刊名: ChemInform, 2015, Vol.46 (45),
来源数据库: Wiley Journal
DOI: 10.1002/chin.201545035
关键词: ring opening reactionsalkenes (benzene compounds)amines (acyclic compounds)regioselective reactionshalogenated carboxylic acids and esters (acyclic compounds)
原始语种摘要: Abstract(#br)A variety of 2‐fluoroallylic amines, ethers, esters, and alkylation products are efficiently obtained with high Z‐selectivity through regioselective activation of gem‐difluorinated cyclopropanes induced by C—C bond cleavage.
全文获取路径: Wiley  (合作)

  • Pd 
  • carboxylic 类羧酸的
  • alkenes 烯属烃
  • alkylation 烷基化
  • selectivity 选择性
  • esters 酯类
  • acyclic 非周期的
  • amines 
  • halogenated 卤代的
  • compounds 化合物