Emergence of Copper‐Mediated Formation of C–C Bonds
作者: Carine MaalikiEmilie ThieryJérôme Thibonnet
作者单位: 1Université François‐Rabelais ISP‐UMR 1282 UFR Sciences et Techniques Parc Grandmont 37000 Tours France
刊名: European Journal of Organic Chemistry, 2017, Vol.2017 (2), pp.209-228
来源数据库: Wiley Journal
DOI: 10.1002/ejoc.201600540
关键词: Synthetic methodsC–C couplingDehydrogenative couplingDecarboxylative couplingDomino reactionsCopper
原始语种摘要: Copper‐catalyzed cross‐coupling reactions have found widespread application in carbon–carbon or carbon–heteroatom bond formation. The relatively low toxicity, ease of handling, and low cost of these versatile complexes make them attractive for the elaboration of new methodologies and for the obtaining of new compounds. We focus on recent methods for the copper‐mediated formation of carbon–carbon bonds illustrated by different coupling reactions: cross‐dehydrogenative coupling, decarboxylative cross‐coupling, Sonogashira‐type reactions, Suzuki‐type reactions, and Neigishi‐type reactions. Domino reactions and, finally, more atypical reactions are also illustrated.
全文获取路径: Wiley  (合作)
影响因子:3.344 (2012)

  • coupling 连接
  • heteroatom 杂原子
  • attractive 有吸引力的
  • carbon 
  • illustrated 以…说明
  • bonds 公债
  • catalyzed 催化的
  • versatile 多方面的
  • Suzuki 铃木牌摩托车
  • relatively 比较