In situ synthesis of a novel transparent poly (methyl methacrylate) resin with markedly enhanced flame retardancy
作者: Saihua JiangYulu ZhuYuan HuGuohua ChenXingxing ShiXiaodong Qian
作者单位: 1School of Mechanical and Automotive Engineering South China University of Technology Wushan Road 381 Guangzhou 510641 PR China
2 State Key Laboratory of Fire Science University of Science and Technology of China Jinzhai Road 96 Hefei Anhui 230027 PR China
3 The Ministry of Scientific Research Chinese People's Armed Police Force Academy Xichang Road 220 Langfang city Hebei 065099 PR China
刊名: Polymers for Advanced Technologies, 2016, Vol.27 (2), pp.266-272
来源数据库: Wiley Journal
DOI: 10.1002/pat.3631
关键词: flame retardancypoly (methyl methacrylate)phosphorus‐containing monomercatalytic charring functionmechanism
原始语种摘要: A novel phosphorus‐containing monomer, (6‐oxido‐6H‐dibenzo[c,e][1,2]oxaphosphinin‐6‐yl)methyl acrylate (DOPO‐AA), is first synthesized and characterized by Fourier transform infrared spectra (FTIR), 1H nuclear magnetic resonance (NMR) and 31P NMR. The monomer is then introduced into poly (methyl methacrylate) (PMMA) matrix via in situ copolymerization to produce a new PMMA based copolymer (PMMA/DOPO‐AA). From UV–vis spectra, microscale combustion calorimeter (MCC) and thermogravimetric analyses (TGA) results, the as‐fabricated PMMA/DOPO‐AA copolymers not only keep relatively high transparency, but also exhibit remarkable improvements in the flame retardancy and thermal stability, such as increased T0.5 by 60.2°C and limited oxygen index (LOI) by 4.1, and...
全文获取路径: Wiley  (合作)