Total Synthesis of (±)‐Waihoensene
作者: Dr. Hongsoo LeeDr. Taek KangProf. Dr. Hee‐Yoon Lee
作者单位: 1Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) 291 Daehak-ro, Yuseong-gu Daejeon 34141 Republic of Korea
刊名: Angewandte Chemie International Edition, 2017, Vol.56 (28), pp.8254-8257
来源数据库: Wiley Journal
DOI: 10.1002/anie.201704492
关键词: natural productstandem cycloaddition reactiontotal synthesistrimethylenemethane diylwaihoensene
原始语种摘要: Abstract(#br)The first total synthesis of waihoensene, a tetracyclic diterpene containing an angular triquinane and a six‐membered ring, with four contiguous quaternary carbon atoms, was achieved through the tandem cycloaddition reaction of an allenyl diazo substrate containing a six‐membered ring via trimethylenemethane (TMM) diyl intermediate.
全文获取路径: Wiley  (合作)

  • cycloaddition 环加
  • membered 有肢的
  • reaction 反酌
  • diazo 重氮
  • tandem 串联机
  • synthesis 合成
  • diterpene 双萜
  • total 总和
  • tetracyclic 四轮列的
  • products 制品