Promotion effect of nickel for Cu–Ni/γ-Al 2 O 3 catalysts in the transfer dehydrogenation of primary aliphatic alcohols
作者: Xiaomei YangXiaomin FuNingning BuLi HanJianfeng WangChengying SongYunlai SuLipeng ZhouTianliang Lu
作者单位: 1College of Chemistry and Molecular Engineering, Zhengzhou University
2Research Center of Heterogeneous Catalysis and Engineering Sciences, School of Chemical Engineering and Energy, Zhengzhou University
刊名: Journal of the Iranian Chemical Society, 2017, Vol.14 (1), pp.111-119
来源数据库: Springer Journal
DOI: 10.1007/s13738-016-0963-2
关键词: Heterogeneous catalysisAlcoholsDehydrogenation
英文摘要: Abstract(#br)Cu–Ni/γ-Al 2 O 3 bimetallic catalysts were developed for anaerobic dehydrogenation of non-activated primary aliphatic alcohols to aldehydes. Systematic investigation about the promotion effect of nickel on the catalytic performance was carried out. Hydrogenation of C=C bond rather than C=O bond, was significantly improved over Cu–Ni/γ-Al 2 O 3 catalyst by introducing nickel, which interprets the good conversion of primary aliphatic alcohols. This work would contribute to design new catalysts for dehydrogenation of primary aliphatic alcohols.
全文获取路径: Springer  (合作)
影响因子:1.467 (2012)

  • aliphatic 无环的
  • Ni 
  • alcohols 醇类
  • effect 效应
  • transfer 转换
  • nickel 
  • primary 一次的