Study of half-sandwich mono and dinuclear complexes of platinum group metals containing pyrazolyl pyridine analogues: Synthesis and spectral characterization
作者: VENKATESWARA RAO ANNAKOTA THIRUMALA PRASADPENG WANGKOLLIPARA MOHAN RAO
作者单位: 1Department of Chemistry, North-Eastern Hill University
2Department of Chemistry, McMaster University
刊名: Journal of Chemical Sciences, 2012, Vol.124 (3), pp.565-575
来源数据库: Springer Journal
DOI: 10.1007/s12039-012-0249-x
关键词: N-donor ligandsmono and binuclear complexesrutheniumrhodiumiridium
英文摘要: Abstract(#br)The chelating ligands 3-chloro-6-(3-pyridyl-1-pyrazolyl)pyridazine ( pp-Cl ) and 3,6-bis(3-pyridyl- 1-pyrazolyl)pyridazine ( bppp ), were prepared by the condensation of pyridylpyrazole and 3,6-dichloropyridazine. The mononuclear complexes [( η 6 -arene)Ru( pp -Cl)Cl] + { η 6 -arene = C 6 H 6 ( 1 ); p - i PrC 6 H 4 Me ( 2 )}, [( η 5 -C 5 Me 5 )M( pp -Cl)] + {M = Rh ( 3 ); Ir ( 4 )}, [( η 6 -arene)Ru( bppp )Cl] + { η 6 -arene = C 6 H 6 ( 5 ); p - i PrC 6 H 4 Me ( 6 )}, [( η 5 -C 5 Me 5 )M( bppp )] + {M =Rh ( 7 ); Ir ( 8 )} as well as the binuclear complexes [{( η 6 -arene)RuCl} 2 (bppp)] 2 + { η 6 -arene =C 6 H 6 ( 9 ); p - i PrC 6 H 4 Me ( 10 )} and [{( η 5 -C 5 Me 5 )MCl} 2 ( bppp )] 2 + {M = Rh ( 11 ); Ir ( 12 )} have been synthesized from...
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影响因子:1.298 (2012)

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关键词翻译
关键词翻译
  • pyrazolyl 吡唑基
  • dinuclear 二核的
  • pyridine 吡啶
  • complexes 联合企业
  • platinum 
  • spectral 谱的
  • sandwich 多层结构材料
  • group 
  • containing 包含的