Kinetic and Thermodynamic Studies of Chlorinated Organic Compound Degradation by Siderite-Activated Peroxide and Persulfate
作者: Ni YanMengjiao LiYali LiuFei LiuMark L. Brusseau
作者单位: 1China University of Geosciences
2University of Arizona
刊名: Water, Air, & Soil Pollution, 2017, Vol.228 (12)
来源数据库: Springer Nature Journal
DOI: 10.1007/s11270-017-3631-y
关键词: Advanced oxidationChlorinated organic compoundsPhosphateActivation energy
原始语种摘要: The efficacy of two oxidant systems, iron-activated hydrogen peroxide (H2O2) and iron-activated hydrogen peroxide coupled with persulfate (S2O8 2−), was investigated for treatment of two chlorinated organic compounds, trichloroethene (TCE) and 1,2-dichloroethane (DCA). Batch tests were conducted at multiple temperatures (10–50 °C) to investigate degradation kinetics and reaction thermodynamics. The influence of an inorganic salt, dihydrogen phosphate ion (H2PO4 ), on oxidative degradation was also examined. The degradation of TCE was promoted in both systems, with greater degradation observed for higher temperatures. The inhibition effect of H2PO4 on the degradation...
全文获取路径: Springer Nature  (合作)
影响因子:1.748 (2012)

  • degradation 减嚣夷酌
  • persulfate 过硫酸盐
  • peroxide 过氧化
  • oxidation 氧化
  • kinetics 动力学
  • chlorinated 氯化了的
  • treatment 处理
  • compounds 化合物
  • values 价值观
  • higher